Radical cyclization {via|by way of|through|by means of} cobalt(III)–carbene radical intermediates {is a|is really a|is actually a|can be a|is often a|is usually a} {powerful|potent|effective|strong|highly effective} {method|technique|approach|strategy|system|process} for the synthesis of (hetero)cycles.…
Understanding the chemical bonding {in the|within the|inside the} catalytic cofactor {of the|from the|in the|on the|with the|of your} Mo nitrogenase (FeMo-co) is foundational for {building|developing|creating|constructing} a mechanistic {picture|image} of biological nitrogen…
Polar intermetallics are an intriguing class of compounds with {complex|complicated} relationships {between|in between|among|amongst|involving} composition and structure {that are|which are|which can be|which might be|that happen to be} not {fully|totally|completely} understood. This…
The tropylium catalyzed carboxylic acid O-H insertion with diazoesters {providing|supplying|offering|delivering|giving} α-hydroxy esters was reported {recently|lately|not too long ago} {through|via|by means of|by way of} an activated carbene {as the|because the} {key|important|crucial|essential}…
Metal sulfides are a {common|typical|frequent|widespread|prevalent|popular} group of extracellular bacterial biominerals. Only {few|couple of|handful of} {cases|instances|circumstances|situations} of intracellular biomineralization {have been|happen to be|have already been} reported {in this|within this} group, {mostly|mainly|largely}…
Our theoretical {treatment|therapy|remedy} of electronic structure in coordination complexes {often|frequently|usually|typically|generally|normally} rests on assumptions of symmetry. Experiments {rarely|seldom|hardly ever} {provide|offer|supply|give|present|deliver} {fully|totally|completely} symmetric systems to study. In {solution|answer|remedy|resolution|option}, fluctuation in solvation, variations…
Hydrogen peroxide (H2O2) plays {an important|an essential|a crucial|a vital} {role|function|part} in {various|numerous|different|a variety of|several|many} signal transduction pathways and regulates {important|essential|crucial|critical|significant|vital} cellular processes. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, monitoring…
{Starting|Beginning} {with the|using the|with all the|together with the} reaction of 2H-cycloheptafuran-2-ones with an enamine, which was {prepared|ready} from 4-tert-butylcyclohexanone and pyrrolidine, benzazulenes {having|getting|possessing|obtaining} {both|each} formyl and tert-butyl groups {were|had been|have…
3d-Metals {have been|happen to be|have already been} identified as {economic|financial} and sustainable {alternatives|options} to palladium, the {frequently|often|regularly} {used|utilized|employed|utilised|applied|made use of} metal in transition-metal-catalyzed cross-couplings. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said…
A topological reference {system|method|program|technique} {is a|is really a|is actually a|can be a|is often a|is usually a} theory that {allows|enables|permits|makes it possible for} the visualization {of the|from the|in the|on the|with the|of…