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Regioselective access to orthogonal Diels-Alder C60 bis-adducts and tris-heteroadducts {via|by way of|through|by means of} avant-garde supramolecular mask {strategy|technique|method|approach|tactic}

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The regioselective poly-functionalization of {highly|extremely|very|hugely} symmetric spherical Ih-C60 is {extremely|very|incredibly|really|particularly|exceptionally} {challenging|difficult} and {usually|generally|typically|normally|commonly|ordinarily} {leads to|results in} the formation of regio-isomeric mixtures not amenable for HPLC purification. {Recently|Lately|Not too long ago},…

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Analytic High-Order {Energy|Power} Derivatives for Metal Nanoparticle-Mediated Infrared and Raman Scattering Spectra {within the|inside the} Framework of Quantum Mechanics/Molecular Mechanics Model with Induced Charges and Dipoles

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This {work|function|perform|operate} is devoted to deriving and implementing analytic second- and third-order {energy|power} derivatives with respect tothe nuclear coordinates and external electric field {within the|inside the} framework {of the|from the|in…

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{Learning|Studying|Understanding|Finding out|Mastering} relationships {between|in between|among|amongst|involving} chemical and physical stability for drug {development|improvement}

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Chemical and physical stabilities are two {key|important|crucial|essential} {features|attributes|functions|characteristics|capabilities|options} {considered|regarded as|deemed|regarded|viewed as|thought of} in pharmaceutical {development|improvement}. Chemical stability is {typically|usually|normally|generally|commonly|ordinarily} reported as a {combination|mixture} of potency and degradation {product|item|solution}. For peptide…

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Photoredox α-Arylation of cyclic ketones

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The direct α-arylation of unactivated carbonyl compounds {using|utilizing|making use of|employing|working with|applying} aryl halides represents a {powerful|potent|effective|strong|highly effective} {method|technique|approach|strategy|system|process} to synthesize criti-cal {building|developing|creating|constructing} blocks for diverse {useful|helpful|beneficial|valuable} compounds. {Numerous|Many|Several|Quite a few|A…

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Machine {Learning|Studying|Understanding|Finding out|Mastering} on a Robotic Platform for the {Design|Style|Design and style} of Polymer-Protein Hybrids

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Polymer-protein hybrids are intriguing {materials|supplies|components} {that can|that may|that will|that could|which will|which can} bolster protein stability in non-native environments, thereby enhancing their utility in diverse medicinal, {commercial|industrial}, and industrial applications. {One|1|A…

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{Development|Improvement} of an untargeted DNA adductomics {method|technique|approach|strategy|system|process} by ultra-high {performance|overall performance|efficiency|functionality} liquid chromatography coupled to high-resolution mass spectrometry

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Cancer {may be|might be|could be|could possibly be|can be|may very well be} initiated by covalent modification of DNA by genotoxic molecules coming from {diet|diet plan|diet program|diet regime|eating plan}, {environment|atmosphere}, inflammation, {and…

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Simulating Redox Potentials of Biomolecules: the Case of Cryptochrome 1 from Arabidopsis thaliana

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Redox reactions play a {key|important|crucial|essential} {role|function|part} in {various|numerous|different|a variety of|several|many} biological processes, {including|such as|which includes|like} photosynthesis and respiration. Quantitative and predictive computational characterization of redox events is {therefore|consequently|as a result|for…

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Aining ten g/ml RNase A (Invitrogen) and 50 g/ml PI (SigmaAldrich

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Ng. Chondrogenic differentiation was induced together with the STEMPRO chondrogenesis differentiation kit