The electrochemical oxidation of sensitive propargylic benzylic alcohols {having|getting|possessing|obtaining} varying substituents is reported. The ther-mal oxidation of propargylic benzylic alcohols presents an acute challenge {in the|within the|inside the} synthesis of…
Nickel(0) catalysts of N-heterocyclic carbenes (NHCs) {that are|which are|which can be|which might be|that happen to be} stabilized by electronic deficient alkenes possess desirable properties of air tolerance and ease of…
Determination {of the|from the|in the|on the|with the|of your} atomic structure of {solid|strong} surfaces {is a|is really a|is actually a|can be a|is often a|is usually a} challenge {that has|which has} resisted…
Prenylation plays {an important|an essential|a crucial|a vital} {role|function|part} in diversifying structure and function of secondary metabolites. {Although|Even though|Though|Despite the fact that|While} {several|a number of|numerous|many|various|quite a few} cyanobactin prenyltransferases {have been|happen…
Computational {studies|research} of {large|big|huge|massive|substantial|significant} molecular systems are {often|frequently|usually|typically|generally|normally} hindered by resource constraints, {such as|like|including|for example|for instance|which include} the {available|accessible|obtainable|offered|readily available|out there} computational time. A {common|typical|frequent|widespread|prevalent|popular} {approach|method|strategy} to {reduce|decrease|minimize|lessen|lower|cut down} the…
Monolayer-protected metal nanoparticles (NPs) {are not|aren’t|usually are not|will not be|are certainly not|are usually not} only promising {materials|supplies|components} {with a|having a|using a} wide {range of|selection of|array of} {potential|possible|prospective} industrial and biological…
Dynamic nuclear polarization {utilizing|using} photoexcited triplet electrons (triplet-DNP) has {great|fantastic|excellent|wonderful|good|terrific} {potential|possible|prospective} for room-temperature hyperpolarization of nuclear spins. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, the polarization transfer to molecules of…
The indolocarbazole derivatives has been shown {great|fantastic|excellent|wonderful|good|terrific} potentials as {one of the|among the|one of many|one of several|among the list of|on the list of} {key|important|crucial|essential} {important|essential|crucial|critical|significant|vital} compounds {in the|within the|inside the}…
High-throughput computational screening for chemical discovery mandates the automated and unsupervised simulation of {thousands of|a large number of|a huge number of} new molecules and {materials|supplies|components}. In {challenging|difficult} {materials|supplies|components} spaces, {such…
Amphotericin B, a long-used antifungal drug, {forms|types} fungicidal ion-permeable channels across cell membranes. {Using|Utilizing|Making use of|Employing|Working with|Applying} solid-state nuclear magnetic resonance spectroscopy and molecular dynamics simulations, we experimentally elucidated the…