Dual Brønsted/Lewis acid catalysis involving environmentally benign, readily accessible protic acid and iron promotes site-selective tert-butylation of electron-rich arenes {using|utilizing|making use of|employing|working with|applying} di-tert-butylperoxide. This transformation inspired the {development|improvement} of…
{Despite|Regardless of|In spite of} the {enormous|huge|massive} developments of asymmetric catalysis, the basis for asymmetric induction is largely {limited|restricted} to spatial interaction {between|in between|among|amongst|involving} substrate and catalyst. Consequently, asymmetric discrimination {between|in…
{Most of|The majority of} chemistry in nanoporous {materials|supplies|components} with {small|little|tiny|modest|smaller|compact} pore sizes and windows is {known|recognized|identified} to {occur|happen|take place} {on the|around the} surface {which is|that is|which can be} in {immediate|instant|quick}…
Cytochromes P450 are versatile heme-based enzymes {responsible for|accountable for} {vital|important|essential|crucial|very important} life processes. {Of these|Of those}, P450cam (substrate camphor) has been most studied. {Despite|Regardless of|In spite of} this, precise mechanisms…
Organometallic intermediates {participate in|take part in} {many|numerous|several|a lot of|quite a few|lots of} multi-catalytic enantioselective transformations directed by a chiral catalyst, {but the|however the} requirement of optimizing two catalyst {components|elements} {is…
{Effective|Efficient|Successful|Powerful|Productive|Helpful} inhibition of sperm motility {using|utilizing|making use of|employing|working with|applying} a spermicide {can be|may be|could be|might be|is often|is usually} a promising {approach|method|strategy} in {developing|creating|building|establishing} non-invasive male contraceptive agents. Copper is {known|recognized|identified}…
The {development|improvement} of {high|higher} efficiency, {excellent|superb|outstanding|exceptional|great|fantastic} selectivity, and super activity metal catalyst for chemical selective hydrogenation of alkynes to olefin is of {great|fantastic|excellent|wonderful|good|terrific} significance {in the|within the|inside the} field {of…
We introduce a novel multi-level enhanced sampling {strategy|technique|method|approach|tactic} grounded on Gaussian accelerated Molecular Dynamics (GaMD). {First|Initial|Very first|1st|Initially}, we propose a GaMD multi-GPUs-accelerated implementation {within the|inside the} Tinker-HP molecular dynamics package.…
The hydrodeoxygenation of guaiacol is modelled {over|more than} a ({100|one hundred}) β-Mo2C surface {using|utilizing|making use of|employing|working with|applying} density functional theory and microkinetic simulations. The thermochemistry {of the|from the|in the|on the|with…
A multi-component {approach|method|strategy} to structurally {complex|complicated} organosulfur {products|goods|items|merchandise|solutions} is described {via|by way of|through|by means of} the nickel-catalyzed 1,2-carbosulfenylation of unactivated alkenes with organoboron nucleophiles and tailored organosulfur electrophiles. {Key|Important|Crucial|Essential} {to…