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Out with Acetonitrile: Water-assisted Accelerated-Aging Synthesis of CuI-Pyrazine Hybrid Materials

Chemexpress November 19, 2024 0 Comments

CuI and pyrazine form three hybrid materials, (Yellow), (Orange), and (Red). In this work, Red was prepared using a green synthetic method, water-assisted accelerated-aging synthesis, for the first time. The…

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Light-driven charge accumulation of a molecular Cu(I) {complex|complicated} for storage of photoredox equivalents

Chemexpress November 18, 2024 0 Comments

The diurnal day/night cycle is presently of {great|fantastic|excellent|wonderful|good|terrific} interest for harvesting solar {energy|power} aimed at rendering {suitable|appropriate} {energy|power} storage schemes. To this {end|finish} we present a noble-metal {free|totally free|free of…

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Balancing high energy density and chemical stability in redox flow batteries with symmetric tetrazines

Chemexpress November 18, 2024 0 Comments

Nonaqueous redox flow batteries are a promising technology for grid-scale energy storage, however, their commercial success relies on identifying redox active materials that exhibit extreme potentials, high solubilities in all…

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Solvation structure and dynamics of Li and LiO2 and their transformation in non-aqueous organic electrolyte solvents from first-principles simulations

Chemexpress November 18, 2024 0 Comments

Density functional theory calculations together with ab initio molecular dynamics (AIMD) simulations have been used to study the solvation, diffusion and transformation of Li+ and LiO2 upon O2 reduction in…

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Organocatalytic Silicon-Free SuFEx reactions for modular synthesis of sulfonate esters and sulfonamides

Chemexpress November 18, 2024 0 Comments

Sulfur(VI) fluoride exchange (SuFEx) click chemistry provides a powerful tool for rapid construction of modular connections. Here, we report a novel catalytic silicon-free SuFEx reaction with sulfonyl fluorides. Under the…

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An Environmentally Benign Supercapacitor Using A Water-dissolvable Ionic Gel

Chemexpress November 18, 2024 0 Comments

An environmentally benign supercapacitor is developed incorporating an ionic liquid, carbon powder, a cellulose separator and a Molybdenum electrode. The ionic liquid is dispersed into a water-dissolvable polymer, poly(vinyl alcohol),…

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Synthetic Studies with the Brevicidine and Laterocidine Lipopeptide Antibiotics Including Analogues with Enhanced Properties and in vivo Efficacy

Chemexpress November 18, 2024 0 Comments

Brevicidine and laterocidine are two recently discovered lipopeptide antibiotics with promising antibacterial activity. Possessing a macrocyclic core, multiple positive charges, and a lipidated N-terminus, these lipopeptides exhibit potent and selective…

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Regulation of 2D DNA Nanostructures by the Coupling of Intrinsic Tile Curvature and Arm Twist

Chemexpress November 17, 2024 0 Comments

The overwinding and underwinding of duplex segments between junctions have been used in designing both left-handed and right-handed DNA origami nanostructures. For a variety of DNA tubes obtained from self-assembled…

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Kinetic and energetic insights in the dissipative non-equilibrium operation of an autonomous light-powered supramolecular pump

Chemexpress November 17, 2024 0 Comments

Natural and artificial autonomous molecular machines operate by constantly dissipating energy coming from an external source to maintain a non-equilibrium state. The in-depth study of these dissipative states is highly…

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Interplay between shape and composition in bimetallic nanoparticles revealed by an efficient optimal-exchange optimization algorithm

Chemexpress November 17, 2024 0 Comments

Despite the large relevance of bimetallic metal nanoparticles for heterogeneous catalysis, the relation between their shape and elemental composition remains elusive. Here, we investigate this relationship by implementing and applying…

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And injure each the microcirculation and tubular epithelium. It has been

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Red NADPH autofluorescence. P , 0.05 compared with Sham Automobile and CLP Vehicle.

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Aining ten g/ml RNase A (Invitrogen) and 50 g/ml PI (SigmaAldrich

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Ng. Chondrogenic differentiation was induced together with the STEMPRO chondrogenesis differentiation kit

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