Illuminating mechanochemical reactions by combining real-time fluorescence emission monitoring and periodic time-dependent density-functional calculations

We {provide|offer|supply|give|present|deliver} a proof-of-principle demonstration {of the|from the|in the|on the|with the|of your} {first|initial|very first|1st|initially} dual-spectroscopic {method|technique|approach|strategy|system|process} for direct and real-time observation of mechanochemical reactions by ball milling, supported by high-level…

Regiocontrolled Allylic Functionalization of Internal Alkene {via|by way of|through|by means of} Selenium-pi-Acid Catalysis Guided by Boron Substitution

The selenium-pi-acid-catalysis has received {increasing|growing|escalating|rising} {attention|interest|focus|consideration} as {powerful|potent|effective|strong|highly effective} tools for olefin functionalization, {but the|however the} regioselectivity is {often|frequently|usually|typically|generally|normally} problematic. Reported herein {is a|is really a|is actually a|can be a|is…