Radical cyclization {via|by way of|through|by means of} cobalt(III)–carbene radical intermediates {is a|is really a|is actually a|can be a|is often a|is usually a} {powerful|potent|effective|strong|highly effective} {method|technique|approach|strategy|system|process} for the synthesis of (hetero)cycles.…
Understanding the chemical bonding {in the|within the|inside the} catalytic cofactor {of the|from the|in the|on the|with the|of your} Mo nitrogenase (FeMo-co) is foundational for {building|developing|creating|constructing} a mechanistic {picture|image} of biological nitrogen…
Polar intermetallics are an intriguing class of compounds with {complex|complicated} relationships {between|in between|among|amongst|involving} composition and structure {that are|which are|which can be|which might be|that happen to be} not {fully|totally|completely} understood. This…
The tropylium catalyzed carboxylic acid O-H insertion with diazoesters {providing|supplying|offering|delivering|giving} α-hydroxy esters was reported {recently|lately|not too long ago} {through|via|by means of|by way of} an activated carbene {as the|because the} {key|important|crucial|essential}…
Metal sulfides are a {common|typical|frequent|widespread|prevalent|popular} group of extracellular bacterial biominerals. Only {few|couple of|handful of} {cases|instances|circumstances|situations} of intracellular biomineralization {have been|happen to be|have already been} reported {in this|within this} group, {mostly|mainly|largely}…